Communications of the ACM
Discovery Shows Promise as Silicon's Replacement in Semiconductors
Energy-dispersive X-ray spectroscopy confirms the researchers' nanostructures are oxygen rich, sulfur poor, and with virtually unchanged copper concentration compared to the material from which they are grown.
Credit: ACS Appl. Mater. Interfaces
Two-dimensional electronic devices could inch closer to their ultimate promise of low power, high efficiency, and mechanical flexibility with a processing technique developed at the U.S. Department of Energy's Oak Ridge National Laboratory.
A team led by Olga Ovchinnikova of ORNL's Center for Nanophase Materials Sciences Division used a helium ion microscope, an atomic-scale "sandblaster," on a layered ferroelectric surface of a bulk copper indium thiophosphate. The result, detailed in "Polarization Control via He-Ion Beam Induced Nanofabrication in Layered Ferroelectric Semiconductors," published in the journal ACS Applied Materials and Interfaces, is a surprising discovery of a material with tailored properties potentially useful for phones, photovoltaics, flexible electronics, and screens.
"Our method opens pathways to direct-write and edit circuitry on 2-D material without the complicated current state-of-the-art multi-step lithographic processes," Ovchinnikova says.
She and colleague Alex Belianinov note that while the helium ion microscope is typically used to cut and shape matter, they demonstrated that it can also be used to control ferroelectric domain distribution, enhance conductivity, and grow nanostructures. Their work could establish a path to replace silicon as the choice for semiconductors in some applications.
"Everyone is looking for the next material — the thing that will replace silicon for transistors," says Belianinov, the lead author. "2-D devices stand out as having low power consumption and being easier and less expensive to fabricate without requiring harsh chemicals that are potentially harmful to the environment."
Reducing power consumption by using 2-D-based devices could be as significant as improving battery performance. "Imagine having a phone that you don't have to recharge but once a month," Ovchinnikova says.
Co-authors of the ACS Applied Materials and Interfaces paper are Vighter Iberi, Alexander Tselev, Michael Susner, Michael McGuire, David Joy, Stephen Jesse, Adam Rondinone, and Sergei Kalinin.
The research was funded through the Laboratory Directed Research and Development program. Some of the work was performed at the Center for Nanophase Materials Sciences, a DOE Office of Science User Facility.
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