Communications of the ACM
Chip-Scale Broadband Optical System Can Sense Molecules in the Mid-Infrared
Schematic of silicon microresonator generating a frequency comb that samples molecules for chemical identification.
Credit: Alexander Gaeta / Columbia Engineering
Researchers at Columbia Engineering have demonstrated a chip-based dual-comb spectrometer in the mid-infrared range that requires no moving parts and can acquire spectra in less than 2 microseconds. The system, which consists of two mutually coherent, low-noise, microresonator-based frequency combs spanning 2,600 nm to 4,100 nm, could lead to the development of a spectroscopy lab-on-a-chip for real-time sensing on the nanosecond time scale.
"Our results show the broadest optical bandwidth demonstrated for dual-comb spectroscopy on an integrated platform," says Alexander Gaeta, David M. Rickey Professor of Applied Physics and of Materials Science and senior author of "Silicon-Chip-Based Mid-Infrared Dual-Comb Spectroscopy," published in the journal Nature Communications.
Creating a spectroscopic sensing device on a chip that can realize real-time, high-throughput detection of trace molecules has been challenging. A few months ago, teams led by Gaeta and Michal Lipson, Higgins Professor of Electrical Engineering, were the first to miniaturize dual-frequency combs by putting two frequency comb generators on a single millimeter-sized chip. They have been working on broadening the frequency span of the dual combs, and on increasing the resolution of the spectrometer by tuning the lines of the comb.
In this current study, the researchers focused on the mid-infrared (mid-IR) range, which, because its strong molecular absorption is typically 10 to 1,000 times greater than those in the visible or near-infrared, is ideal for detecting trace molecules. The mid-IR range effectively covers the "fingerprint" of many molecules.
The team performed mid-IR dual-comb spectroscopy using two silicon nanophotonic devices as microresonators. Their integrated devices enabled the direct generation of broadband mid-infrared light and fast acquisition speeds for characterizing molecular absorption.
"Our work is a critical advance for chip-based dual-comb spectroscopy for liquid/solid phase studies," ssays aid Mengjie Yu, lead author of the paper and a Ph.D. student in Gaeta's lab. "Our chip-scale broadband optical system, essentially a photonic lab-on-a-chip, is well-suited for identification of chemical species and could find a wide range of applications in chemistry, biomedicine, material science, and industrial process control."
The Nature Communications study is authored by Mengjie Yu (Department of Applied Physics and Applied Mathematics, Columbia Engineering; School of Electrical and Computer Engineering, Cornell University), Yoshitomo Okawachi (department of applied physics and applied mathematics, Columbia Engineering), Austin G. Griffith (School of Applied and Engineering Physics, Cornell University), Nathalie Picqué (Max-Planck-Institut für Quantenoptik; Ludwig-Maximilians-Universität München, Fakultät für Physik; Institut des Sciences Moléculaires d'Orsay, CNRS, Univ. ParisSud, Université ParisSaclay), Michal Lipson (Department of Electrical Engineering, Columbia Engineering), and Alexander L. Gaeta (department of applied physics and applied mathematics, Columbia Engineering).
The study was supported by the Defense Advanced Research Projects Agency (W31P4Q1510015), the Air Force Office of Scientific Research (FA95501510303), and the National Science Foundation (ECS0335765, ECCS1306035). This work was performed in part at the Cornell NanoScale Facility, a member of the National Nanotechnology Infrastructure Network, which is supported by the National Science Foundation (grant ECS0335765).
The authors declare no competing interests.
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